Dirac's coup
Dirac thus thought to try an equation that was first order in both space and time. One could, for example, formally take the relativistic expression for the energy
replace p by its operator equivalent, expand the square root in an infinite series of derivative operators, set up an eigenvalue problem, then solve the equation formally by iterations. Most physicists had little faith in such a process, even if it were technically possible.
As the story goes, Dirac was staring into the fireplace at Cambridge, pondering this problem, when he hit upon the idea of taking the square root of the wave operator thus:
On multiplying out the right side we see that, in order to get all the cross-terms such as ∂x∂y to vanish, we must assume
with
Dirac, who had just then been intensely involved with working out the foundations of Heisenberg's matrix mechanics, immediately understood that these conditions could be met if A, B, C and D are matrices, with the implication that the wave function has multiple components. This immediately explained the appearance of two-component wave functions in Pauli's phenomenological theory of spin, something that up until then had been regarded as mysterious, even to Pauli himself. However, one needs at least 4 × 4 matrices to set up a system with the properties required — so the wave function had four components, not two, as in the Pauli theory, or one, as in the bare Schrödinger theory. The four-component wave function represents a new class of mathematical object in physical theories that makes its first appearance here.
Given the factorization in terms of these matrices, one can now write down immediately an equation
with κ to be determined. Applying again the matrix operator on both side yields
On taking κ = mc/ħ we find that all the components of the wave function individually satisfy the relativistic energy–momentum relation. Thus the sought-for equation that is first-order in both space and time is
Setting
we get the Dirac equation as written above:
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